Stalk -
As always - you dig in and get your number-crunching machine going and then add the icing to the cake.
I was gonna mention in my posts -- and at the minimum -- 2013 but the question was centered on the early 2000s.
Then adding to the above, and if it was a bit more open-ended (the thread), I would have put 2013 at the front of the pack too. At 13-2 that was the team that we'll always look at and say "coulda, woulda, shoulda". A rock-crushing group I recall that in the fourth game they gave up a TD (the first points of the season) and everyone went nuts as the "plan" was to "goose egg" everyone (it was 45-0 and Schmidt put in the 9th grade team in the third-quarter so that the final was 45-7).
That team set the record at Neshaminy for total points (531) and featured the 4A Player of the Year in D'Andre Pollard (he finished just shy of 3,000 yards with 2,929 and 39 TDs). Luke Carrezola was also a USA Today all PA performer (he, Pollard and Denny Lord - the FB - were all 1st team All State) with Carrezola starring at UConn and then getting a look by a few NFL teams before playing with the Salt Lake club in one of those short lived pro leagues of the late teens - Pollard went to Temple but was dogged by injury as was Lord at West Chester).
Of course, the short circuit in 2013 was the Eastern Final against St. Joe's which they lost 37-21. Curiously, they had no passing game and relied on the brute running of Lord and his compatriot FB, Blake Sullivan (each 6-1 and then 224 and 242 respectively) in addition to Pollard. And run they could as they were trouncing The Prep on the ground. But still behind to start the the second half (they were down 19-13) they took the kickoff and were in the redzone on another 80 yard, 5 yard a run drive when Lord was breaking free. With a habit of holding the ball like a loaf of bread all season long St. Joe's certainly had noticed and this time a "strip" worked. The loose ball was then picked up and returned 90 yards by a St. Joe's player for a score to make it 26-13. Neshaminy just couldn't do enough after that as it was really a back breaker (Lord did score for Neshaminy on a long run to redeem himself -- and as he was a gamer so you couldn't blame his efforts all year long at FB and linebacker).
Of course, St. Joe's crushed a solid but not spectacular PCC in the final, 35-10, and observers of the day felt Neshaminy would have produced a similar result.
THAT was the year that really got away from the 'Skins.
Those other seasons were certainly good (an 11-2 2007 team and 12-2 2008 group) with both of them having shots. Still, I know you'll recall they walked into a face punch down in your neck of the woods when Ridley ended their 2007 run in the playoffs and then it was North Penn in the D1 final that got them in 2008.
I thought both those later 2000 teams had great potential but sorta underperformed in the playoffs in their losses. But the 2013 team - now that was a group. In fact, they had so many players people were talking about them in 2008 and 2009 when the kids were in junior high - we all just couldn't wait (ugh, "The Fumble" -- as they call it - cost Schmidt another trophy). Course, they had all the pieces save for one thing - a QB. As it was, they actually used Lord in the shotgun and just gave him the ball and said "run". He threw a few passes too (quite a good athlete). Plus Pollard - he was elusive, fast, shifty, quick -- everything you'd want.
Anyway, if you took those six years -- 2001, 2004, 2005, 2007, 2008 and 2013 -- you see an overall of 74-10 and they certainly represent perhaps the best years of the Schmidt era which ran from 1995 to 2013.